In order for your application to run on the Blue Gene, it must be compiled against the Blue Gene MPI libraries for the Power architecture. Because the Blue Gene is a specialized computer, there are certain limitations not found in other systems:
The Blue Gene comes with two sets of compilers: the GNU compiler suite (eg. gcc), and the IBM compiler suite (eg. xlc). Each suite also has an associate cross-compiler for building parallel applications. The cross-compilers all have names beginning with 'blrts_':
IBM compilers: blrts_c89, blrts_cc, blrts_f90, blrts_fort77, blrts_xlc, blrts_xlC, blrts_xlc++, blrts_xlf90, blrts_c99, blrts_f77, blrts_f95, blrts_xlf, blrts_xlf95
GNU compilers: blrts_g++, blrts_gcc, blrts_g7
The MPI and various Blue Gene header files are in the directory /bgl/BlueLight/ppcfloor/bglsys/include/ . You will therefore need to include -I/bgl/BlueLight/ppcfloor/bglsys/include with your compiler flags.
Every Blue Gene program must be linked with at least four libraries which are in the directory /bgl/BlueLight/ppcfloor/bglsys/lib/ . The main 4 required libraries are libmpich.rts.a, libdevices.rts.a, libmsglayer.rts.a, and librts.rts.a. That is all you need for C and Fortran. The library libcxxmpich.rts.a is also required to compile C++ code. The compiler option -fno-underscoring is required by blrts_g77.
There is more detailed information on compiling here.
Here is a sample Makefile to use as a reference.